INVESTIGATION OF THE SOLUTION PHASE CHEMILUMINESCENCE OF 1,2,4-TRIAZOLE DERIVATIVES

Abstract:

We discovered and studied the chemiluminescence occurring during the oxidation of 3-bromo-5-hydrazino-1-(thietan-3-yl)-1H-1,2,4-triazole with superoxide anion. The chemiluminescence wavelength interval was 400-590 nm with the maxima (at 436 and 540 nm) matching the peak fluorescence wavelengths of the reaction products. The possible reaction products were determined by NMR spectroscopy, mass spectrometry, IR and UV spectroscopy. The quantum yield of chemiluminescence was 10-9 E/mol

Тип: Article